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Síntesis hidrotermal de AlPO-5 y SAPO-5 y su evaluación catalítica en la oligomerización de propileno

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dc.contributor.authorRuiz Llano, Jorgespa
dc.contributor.authorArroyave Manco, Juan Camilospa
dc.contributor.authorArboleda Echavarría, Johana Catalinaspa
dc.contributor.authorEchavarría Izasa, Adriana Patriciaspa
dc.date.accessioned2020-02-03 00:00:00
dc.date.accessioned2022-06-17T20:20:03Z
dc.date.available2020-02-03 00:00:00
dc.date.available2022-06-17T20:20:03Z
dc.date.issued2020-02-03
dc.description.abstractLos aluminofosfatos y silico-aluminofosfatos son familias de mallas moleculares que presentan sistemas de poros ordenados con disposición alternada de AlO4 y PO4. Estas pueden usarse en la reacción de oligomerización de propileno debido a sus propiedades para promover la obtención de hidrocarburos de cadenas más grandes como el Diesel. En el presente trabajo se sintetizó AlPO-5 y SAPO-5 y se evaluó su actividad catalítica en la oligomerización de propileno. Las mallas moleculares obtenidas se caracterizaron por difracción de rayos X (XRD), análisis termogravimétrico (TGA), espectroscopía de absorción atómica (AA), desorción de amoniaco a temperatura programada (NH3-TPD) y microscopía electrónica de barrido (SEM). Los productos de la reacción se analizaron mediante cromatografía de gases (GC). Se obtuvo un mayor rendimiento en la proporción de oligómeros pesados en la reacción luego de las impregnaciones de Cr y Ni al material AlPO-5, siendo el material Cr 3% AlPO-5 el de mayor rendimiento.spa
dc.description.abstractAluminophosphates and silicoaluminophospates are molecular sieves families with ordered pore systems with an alternative accommodation of AlO4 and PO4. This molecular sieves can be use like catalyst in propylen oligomerization reaction due their textural properties and selectivity toward some products for contribute to obtaining olefins of carbon chains longer achieving thus the synthesis of sulfur free liquid fuels. In this work, AlPO-5 and SAPO-5 were synthetize and was evaluated its catalytic activity in propylen oligomerization. Molecular sieves obtained were characterized by x-ray diffraction (XRD), thermal gravimetric analysis (TGA), atomic absorption spectrometry (AA), ammonia temperature programmed desorption (NH3-TPD) and scanning electronic microscopy (SEM). The reaction products were analyzed by gas chromatography (GC). A higher yield was obtained in the proportion of heavy oligomers after impregnation of Cr and Ni on AlPO-5, being Cr 3% AlPO-5 the catalyst with the highest yield.eng
dc.format.mimetypeapplication/pdfspa
dc.identifier.doi10.24050/reia.v17i33.1260
dc.identifier.eissn2463-0950
dc.identifier.issn1794-1237
dc.identifier.urihttps://repository.eia.edu.co/handle/11190/5057
dc.identifier.urlhttps://doi.org/10.24050/reia.v17i33.1260
dc.language.isospaspa
dc.publisherFondo Editorial EIA - Universidad EIAspa
dc.relation.bitstreamhttps://revistas.eia.edu.co/index.php/reveia/article/download/1260/1271
dc.relation.citationeditionNúm. 33 , Año 2020spa
dc.relation.citationendpage11
dc.relation.citationissue33spa
dc.relation.citationstartpage33002 pp. 1
dc.relation.citationvolume17spa
dc.relation.ispartofjournalRevista EIAspa
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dc.rightsRevista EIA - 2020spa
dc.rights.accessrightsinfo:eu-repo/semantics/openAccessspa
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dc.rights.creativecommonsEsta obra está bajo una licencia internacional Creative Commons Atribución-NoComercial-SinDerivadas 4.0.spa
dc.rights.urihttps://creativecommons.org/licenses/by-nc-nd/4.0spa
dc.sourcehttps://revistas.eia.edu.co/index.php/reveia/article/view/1260spa
dc.subjectsilico-aluminofosfatospa
dc.subjectimpregnaciónspa
dc.subjectoligomerización de propilenospa
dc.subjectcatálisisspa
dc.subjectsilicoaluminophosphateeng
dc.subjectimpregnationeng
dc.subjectpropylen oligomerizationeng
dc.subjectcatalysiseng
dc.titleSíntesis hidrotermal de AlPO-5 y SAPO-5 y su evaluación catalítica en la oligomerización de propilenospa
dc.title.translatedAlPO-5 and SAPO-5 hydrothermal synthesis and catalytic propylen oligomerizationeng
dc.typeArtículo de revistaspa
dc.typeJournal articleeng
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dc.type.coarversionhttp://purl.org/coar/version/c_970fb48d4fbd8a85spa
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dc.type.driverinfo:eu-repo/semantics/articlespa
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